HENKEL SURFACE TECHNOLOGIES -- ALUMIPREP 33 -- 6850-01-096-2274
===================== Product Identification ===================== Product ID:ALUMIPREP 33 MSDS Date:04/09/1998 FSC:6850 NIIN:01-096-2274 === Responsible Party === Company Name:HENKEL SURFACE TECHNOLOGIES Address:32100 STEPHENSON HWY City:MADISON HEIGHTS State:MI ZIP:48071 Country:US Info Phone Num:248-583-9300 Emergency Phone Num:(800)424-9300 Preparer's Name:SULINDA LEFFINGWELL Chemtrec Ind/Phone:(800)424-9300 CAGE:1N6B3 === Contractor Identification === Company Name:GOURMET INQUE LTD Address:191 STANLEY ST Box:City:ELK GROVE VILLAGE State:IL ZIP:60007-1555 Country:US Phone:847-296-6192/FAX: 800-542-1042 Contract Num:SP0450-01-M-D468 CAGE:0TNN7 Company Name:HENKEL SURFACE TECHNOLOGIES Address:32100 STEPHENSON HWY Box:City:MADISON HEIGHTS State:MI ZIP:48071 Country:US Phone:248-583-9300 Contract Num:SP0450-00-M-SB97 CAGE:1N6B3 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID CAS:7664-38-2 RTECS #:TB6300000 Minumum % Wt:10. Maxumum % Wt:30. Other REC Limits:NIOSH TWA: 1 MG/M3 OSHA PEL:1 MG/M3 OSHA STEL:3 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYLENE GLYCOL N-BUTYL ETHER CAS:111-76-2 RTECS #:KJ8575000 Minumum % Wt:10. Maxumum % Wt:30. Other REC Limits:NIOSH TWA:24MG/M3 OSHA PEL:240 MG/M3;50 PPM ACGIH TLV:121 MG/M3;25 PPM Ingred Name:POTASSIUM FLUORIDE CAS:7789-23-3 RTECS #:TT0700000 Minumum % Wt:1. Maxumum % Wt:10. Other REC Limits:NIOSH:2.5MG/M3 (F) OSHA PEL:2.5 MG/M3 AS F ACGIH TLV:2.5 MG/M3 AS F ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE IDENTIFIED FOR PRODUCT AS WHOLE Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYE CONTACT: THIS PRODUCT IS SEVERELY IRRITATING AND MAY CAUSE IRREVERSIBLE DAMAGE INCLUDING BURNS AND BLINDNESS. SKIN CONTACT: CORROSIVE TO SKIN. MAY CAUSE SEVERE IRRITATION AND BURNS. THE SENSATION MAY BE DELAYED. SKIN ABSORPTION: A COMPONENT MAY BE HARMFUL/FATAL IF ABSORBED THROUGH THE SKIN. INGESTION: MAY PRODUCE CORROSIVE DAMAGE TO GI TRACT. LARGE AMOUNTS MAY RESULT IN FLUORIDE POISONING CAUS ING SEVERE BONE CHANGES, PAIN, PULMONARY FIBROSIS, ANEMIA, ANOREXIA, DENTAL EFFECTS AND POSSIBLE DEATH. INHALATION: MAY CAUSE SEVERE IRRITATION, BURNS, WHEEZING, PULMONARY EDEMA, PNEUMONITIS. REPEATED BREATHING MAY CAUSE FLUOROSIS. Explanation of Carcinogenicity:NO INFORMATION AVAILABLE FOR PRODUCT. ACGIH RATES POTASSIUM FLUORIDE AS A CLASS A4-NOT CLASSIFIABLE AS A HUMAN CARCINOGEN (RELATED TO FLUORIDES). Effects of Overexposure:EYE CONTACT: THIS PRODUCT IS SEVERELY IRRITATING AND MAY CAUSE IRREVERSIBLE DAMAGE INCLUDING BURNS AND BLINDNESS. SKIN CONTACT: CORROSIVE TO SKIN. MAY CAUSE SEVERE IRRITATION AND BURNS. THE SENSATION MAY BE DELAYED. INGESTION: MAY PRODUCE CORROSIVE DAMAGE TO GASTROINTESTINAL TRACT. LARGE AMOUNTS MAY RESULT IN FLUORIDE POISONING CAUSING SEVERE BONE CHANGES, PAIN, PULMONARY FIBROSIS, ANEMIA, ANOREXI A, DENTAL EFFECTS AND POSSIBLE DEATH. INHALATION: MAY CAUSE SEVERE IRRITATION, BURNS, WHEEZING, PULMONARY EDEMA, PNEUMONITIS. Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN AND RESPIRATORY DISORDERS ======================= First Aid Measures ======================= First Aid:EYES-RINSE IMMEDIATELY WITH PLENTY OF WATER FOR 15 MINUTES. SEEK IMMEDIATE MEDICAL ATTENTION. SKIN-IMMEDIATELY REMOVE CONTAMINATED CLOTHES. FLUSH WITH LOTS OF WATER. SEEK IMMEDIATE MEDICAL ATTENTION. INGESTED-GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING! IF CONSCIOUS, GIVE 1-2 GLASSES OF WATER OR MILK. NEVER GIVE ANTHING BY MOUTH TO A VICTIM WHO IS UNCONSCIOUS OR IS HAVING CONVULSIONS. INHALED-REMOVE TO FRESH AIR. SEEK MEDICAL ATTENTION IF SYMTOMS DEVELOP OR PERSIST. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=62.8C, 145.F Extinguishing Media:USE MEDIA SUITABLE FOR THE SURROUNDING FIRES. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:FIRE AND EXPLOSION HAZARDS ARE MODERATE WHEN THIS PRODUCT IS EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND TO SOME DISTANT SOURCE OF IGNITION AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEAN-UP. ABSORB SPILL WITH ABSORBENT MATERIAL. SHOVEL MATERIAL INTO APPROPRIATE CONTAINER FOR DISPOSAL. DISPOSE OF COLLECTED MATRIAL IN ACCORDANCE WITH REGULATIONS. Neutralizing Agent:NOT PROVIDED ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. DO NOT GET IN EYES, ON SKIN OR CLOTHING. WASH THOROUGHLY AFFTER HANDLING. DO NOT INHALE VAPORS OR M ISTS. KEEP PPRODUCT AWAY FROM HEAT, SPARK OR OPEN FLAME. FOR INDUSTRIAL USE ONLY. Other Precautions:WARNING! CORROSIVE AND TOXIC. "EMPTY" CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERSA TO HEAT, FLAME, SPARK S, STATIC ELECTRICITY OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION IS NOT SUFFICIENT TO EFFECTIVELY PREVENT BUILDUP OF AEROSOLS OR VAPORS, APPROPRIATE NIOSH/MSHA RESPIRATORY PROTECTION MUST BE PROVIDED. Ventilation:USE GENERAL VENTILATION AND USE LOCAL EXHAUST WHERE POSSIBLE, IN CONFINED OR ENCLOSED SPACES. Protective Gloves:IMPERVIOUS Eye Protection:WEAR CHEMICAL GOGGLES; FACE SHIELD (IF SPLASHING IS POSSIBLE). Other Protective Equipment:EYE WASH STATION & EMERGENCY SHOWER SHOULD BE IN CLOSE PROXIMITY. USE OF IMPERVIOUS APRON AND SHOES SUGGESTED. Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health CODE: 234449. ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT ESTABLISHED. CNS=CENTRAL NERVOUS SYSTEM. GI=GASTROINTESTIN AL. ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:>93.3C, 200.F Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:NOT DETERMINED Vapor Density:N/D Volatile Org Content %:14 Spec Gravity:1.1 - 1.2 pH:<2 Evaporation Rate & Reference:NOT DETERMINED Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID - SLIGHT SOLVENT ODOR Percent Volatiles by Volume:N/D Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS Stability Condition to Avoid:KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND/OR LOW MOLECULAR WEIGHT HYDROCARBONS. MAY LIBERTAE HYDROGEN FLUORIDE. =================== Toxicological Information =================== Toxicological Information:NO INFORMATION AVAILABLE FOR THIS PRODUCT. THE MAIN OCCUPATIONAL ROUTES OF EXPOSURE TO FLUORIDE COMPOUNDS ARE INHALATION & INGESTION; HOWEVER, FLUORIDES MAY BE HARMFUL OR FATAL IF ABSORBED THROUGH THE SKIN. EXPOSURE TO FLUORIDE COMPOUNDS MAY RESULT IN SEVERE IRRITATION OR BURNS TO THE EYES, SKIN, GASTROINTESTINAL AND RESPIRATORY SYSTEMS. CONTACT WITH FLUORIDE COMPOUNDS MAY NOT BE IMMEDIATELY EVIDE NT DUE TO DELAYED ONSET OF PAIN FOLLOWING EXPOSURE. PHSOPHORIC ACID IS A SEVERE SKIN, EYE & RESPIRATORY SYSTEM IRRITANT. REPEATED EXPOSURE MAY CAUSE BRONCHITIS. 2-BUTOXYETHANOL IS HARMFUL ON INGESTION , INHALATION OR SKIN ABSORPTION ===================== Ecological Information ===================== Ecological:NO DATA AVAILABLE ON PRODUCT. BECAUSE OF LOW PH OF THIS PRODUCT, IT WOULD BE EXPECTED TO PRODUCE SIGNIFIGANT ECOTOXICITY UPON EXPOSURE TO AQUATIC ORGANISMS & AQUATIC SYSTEMS. COMPONENT ANALYSIS: ETHYL ENE GLYCOL N-BUTYL ETHER (2-BUTOXYETHANOL): LC 50 (96 HR) BLUEGILL: 1490 MG/L. COND: STATIC, 23 DEGREES C; LC 50 (24 HR) GOLDFISH: 1650-1700 MG/L; LC50 (24 HR) WATER FLEA: 1720 MG/L. ENVIRONEMNTAL FAT E: NO DATA AVAILABLE CONCERNING THE ENVIRONMENTAL FATE, BIODEGRADATION OR BIOCONCENTRATION FOR THIS PRODUCT. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. THIS MATERIAL IS A RCRA HAZARDOUS WASTE D002, CORROSIVE. =================== MSDS Transport Information =================== Transport Information:PLEASE REFER TO THE CONTAINER LABEL FOR TRANSPORTATION INFORMATION. ===================== Regulatory Information ===================== SARA Title III Information:ETHYLENE GLYCOL N-BUTYL ETHER (CAS# 111-76-2): SARA 313 : FORM R REPORTING REQUIRED FOR 1% DEMINIMUS CONCENTRATION. PHOSPHORIC ACID (CAS # 7664-38-2): FORM R REPORTING REQUIRED FOR 1% DEMINIMUS CONCEN TRATION. SARA 311/312: ACUTE: YES; CHRONIC: YES; FIRE: YES; PRESSURE: NO; REACTIVE: NO. Federal Regulatory Information:THIS MATERIAL IS A RCRA HAZARDOUS WASTE D002, CORROSIVE. CERCLA: ETHYLENE GLYCOL N-BUTYL ETHER- STATUTORY RQ=1 POUND ( 0.454 KG). PHOSPHORIC ACID: FINAL RQ = 5000 LBS (2270 KG). ALL COMPONENTS ARE ON THE US EPA TSCA INVENTORY LIST. State Regulatory Information:NO GENERAL PRODUCT INFORMATION. COMPONENT ANALYSIS - STATE: ETHYLENE GLYCOL N-BUTYL ETHER CAS # 111-76-2-CA-YES; FL-YES, MA-YES, NJ-YES, PA-YES; PHOSPHORIC ACD CAS # 7664-38-2- CA-YES, FL-YES, MA-YES, MN-YES, NJ-YES, PA-YES; POTASSIUM FLUORIDE (RELATED TO FLUORIDES) CAS # 7789-23-3-- CA-YES, FL-NO, MA-NO, MN-YES, NJ-YES, PA-YES. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.