MALLINCKRODT BAKER, INC. -- AMMONIUM SULFATE -- -
===================== Product Identification ===================== Product ID:AMMONIUM SULFATE MSDS Date:12/08/1996 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2154 Resp. Party Other MSDS Num.:A6192 Preparer's Name:STRATEGIC SERVICES DIV. Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM SULFATE CAS:7783-20-2 RTECS #:BS4500000 Minumum % Wt:99. Maxumum % Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL,RAT, LD50: 2840 MG/KG. Reports of Carcinogenicity:NTP:NO IARC:NO Health Hazards Acute and Chronic:EMERGENCY OVERVIEW : WARNING! CAUSES IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED. INHALTION: CAUSES IRRITATION TO THE RESPIRATORY TRACT. INGESTION: CAUSES IRRITATION T O GASTROINTESTINAL TRACT. IT PRESENTS LITTLE TOXICITY UNLESS LARGE AMOUNTS ARE INGESTED, IN WHICH CASE, VOMITING AND DIARRHEA ARE LIKELY. SKIN CONTACT: CAUSES IRRITATION TO SKIN. EYE CONTACT: CAUSES I RRITATION, REDNESS AND PAIN. CHRONIC: NO INFORMATION FOUND. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: COUGHING, SHORTNESS OF BREATH. INGESTION: NAUSEA, VOMITING, AND DIARRHEA. SKIN CONTACT: REDNESS, ITCHING AND PAIN. EYE CONTACT: IRRITATION, REDNESS AND PAIN. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHALTION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDI CAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. SKIN CONTACT: FLUSH EXPOSED SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHIN G AND SHOES. GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES BEFORE REUSE. EYE CONTACT: FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER LIDS OCCASIONALL Y. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT CONSIDERED TO BE A FIRE HAZARD. USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:IN EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:MAY EXPLODE IF MIXED WITH OXIDIZERS, SUCH AS POTASSIUM NITRATE, POTASSIUM NITRITE, AND POTASSIUM CHLORATE. FLAMMABLE AMMONIA GAS MAY BE RELEASED IN A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY BE USED TO AVOID DUST DISPERSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER, STORE IN COOL, DRY, VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE MATERIALS. CONTAINERS OF THIS PRODUCT MAY BE HAZARDOUS WHEN EMPTY SINCE T HEY RETAIN PRODUCT RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE EXPOSURE TO DUST OR MIST IS APPARENT, A HALF-FACE DUST/MIST RESPIRATOR MAY BE WORN. FOR EMERGENCIES OR INSTANCES WHERE THE EXPOSURE LEVELS ARE NOT KNOWN, USE A FULL-FACE POSITIVE PRESSURE, AIR-S UPPLIED RESPIRATOR. WARNING: AIR-PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN DEFICIENT ATMOSPHERES. Ventilation:LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED. LOCAL EXHAST GENERALLY PREFERRED BECAUSE IT CAN CONTROL CONTAMINANT EMISSIONS AT SOURCE. Protective Gloves:WEAR IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT. Eye Protection:USE CHEMICAL SAFETY GOGGLES AND/OR FULL FACE SHIELD FOR DUSTING OR SPLASHING Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, GLOVES, LAB COAT, APRON COVERALLS AS APPROPRIATE, TO PREVENT SKIN CONTACT. MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. Supplemental Safety and Health SYNONYMS: DIAMMONIUM SULFATE, SULFURIC ACID, DIAMMONIUM SALT, ACTAMASTER, DOLAMIN, MASCAGNITE. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:=235.C, 455.F M.P/F.P Text:235-280C (455-536F) Vapor Pres:NO INFO Vapor Density:NO INFO Spec Gravity:1.77 @50C(122F) pH:5.5 Evaporation Rate & Reference:NO INFO (BUAC=1) Solubility in Water:APPRECIABLE. Appearance and Odor:FINE WHITE GRANULES OR CRYSTALS; SLIGHT AMMONIA ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SODIUM HYPOCHLORITE, POTASSIUM PLUS AMMONIUM NITRATE, POTASSIUM CHLORATE, POTASSIUM NITRITE, AND SODIUM-POTASSIUM POWDER PLUS AMMONIUM NITRATE, AND OTHER STRONG OXIDIZERS Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. MAINTAIN AT TEMPERATURES BELOW 513C (955F). AVOID HEAT, INCOMPATIBLES. Hazardous Decomposition Products:MAY EMIT AMMONIA, OXIDES OF SULFUR, OXIDES OF NITROGEN, AND OXIDES OF CARBON. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:ORAL, RAT, LD50: 2840 MG/KG INVESTIGATED AS A MUTAGEN. CANCER LISTS: AMMONIUM SULFATE (7783-20-2): NTP CARCINOGEN: KNOWN: NO; ANTICIPATED: NO. IARC CATEGORY: NONE. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHAT CANNOT BE SAVED FOR RECYCLING SHOULD BE MANAGED IN AN APPROVED WASTE DISPOSAL FACILITY. DISPOSE OF CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REQUIREMENTS. USE, O R CONTAMINATION OF THIS PRODUCT MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE AND LOCAL DISPOSAL REGULA TIONS MAY DIFFER FROM FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:FEDERAL, STATE, AND INTERNATIONAL REGULATIONS - PART 1: INGREDIENT: AMMONIUM SULFATE (7783-20-2): SARA 302: RQ NO ; TPQ NO. SARA 313: LIST NO; CHEMICAL CATG. NO. FEDERAL, STATE, AND INTERNATIONAL REG ULATIONS - PART2: INGREDIENT: AMMONIUM SULFATE (7783-20-2): CERCLA, NO; RCRA 216.33, NO; TSCA, 8(D), NO. Federal Regulatory Information:CHEMICAL INVENTORY STATUS - PART 1: INGREDIENT: AMMONIUM SULFATE (7783-20-2): TSCA, YES; EC,YES; JAPAN, YES; AUSTRALIA, YES. CHEMICAL INVENTORY STATUS - PART 2: INGREDIENT: AMMONIUM SULFATE (7783-20-2 ): KOREA, YES; CANADA DSL, YES; CANADA NDSL, NO; PHIL., YES. CHEMICAL WEAPONS CONVENTION: NO. TSCA12(B): NO. CDTA: NO. SARA 311/312: ACUTE: YES; CHRONIC: NO; FIRE: NO; PRESSURE: NO; REACTIVE: NO; (PUR E / SOLID). ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.