NATIONAL REFRIGERANTS INC -- REFRIGERANT 12 -- 6830-00-106-1656
===================== Product Identification ===================== Product ID:REFRIGERANT 12 MSDS Date:06/01/1988 FSC:6830 NIIN:00-106-1656 === Responsible Party === Company Name:NATIONAL REFRIGERANTS INC Address:89 WATER ST City:BRIDGETON State:NJ ZIP:08302-2545 Country:US Info Phone Num:609-455-4555 Emergency Phone Num:609-455-4555/800-424-9300 CHEMTREC Preparer's Name:T. NAPRAVA, DR. OF Q.C. CAGE:4J994 === Contractor Identification === Company Name:NATIONAL REFRIGERANTS INC Address:661 KENYON AVE Box:City:BRIDGETON State:NJ ZIP:08302 Country:US Phone:800-262-0012/215-698-6620 CAGE:4J994 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: 100% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 1000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANAESTHETIC EFFECTS, TEMPORARY ALTERATION OF THE HEART'S ELECTRICAL ACTIVITY WITH IRREGULAR PULSE, PALPITATIONS OR IRREGULAR PULSE, ASPHYXIATION DUE TO E XCLUSION OF OXYGEN. SKIN PERMEATION APPEARS UNLIKELY. THERE ARE NO REPORTS OF SKIN SENSITIZATION. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES: MILD IRRITANT. SKIN:NOT IRRITATING, HOWEVER LIQUID CONTACT CAN CAUSE FROSTBITE. INHALATION: DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, LOSS OF CONSCIOUSNESS, DEATH. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF HEART DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER.SEE DOCTOR. SKIN:FLUSH WITH WATER.TREAT FOR FROSTBITE IF NECESSARY. INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED.SEE DOCTOR. INGESTION:SEE DOCTO R IF NECESSARY. NOTE TO PHYSICIAN:BECAUSE OF POSSIBLE DISTURBANCE OF CARDIAC RYTHM, CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE, SHOULD BE USED WITH SPECIAL CAUTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:AS APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:CYLINDERS MAY RUPTURE UNDER FIRE CONDITIONS. FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA, ESPECIALLY LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE SCBA FOR LARGE SPILLS. Neutralizing Agent:NONE APPLICABLE FOR THIS MATERIAL ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT AND IGNITION SOURCES. KEEP CONTAINERS CLOSED. DO NOT HEAT ABOVE 125 F. Other Precautions:AVOID BREATHING VAPORS AND LIQUID CONTACT WITH SKIN OR EYES. USE ONLY IN WELL VENTILATED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATORY PROTECTION NORMALLY REQUIRED. USE SCBA IF LARGE RELEASE OCCURS. Ventilation:MECHANICAL (GENERAL) VENTILATION. LOCAL EXHAUST SHOULD BE USED WHEN LARGE AMOUNTS ARE RELEASED. Protective Gloves:LINED BUTYL GLOVES. Eye Protection:CHEMICAL SPLASH GOGGLES. Other Protective Equipment:SAFETY SHOES. Work Hygienic Practices:STANDARD WORK HYGENIC PRACTICES. Supplemental Safety and Health NATIONAL REFRIGERANTS BUYS BULK QUANTITIES FROM SEVERAL MANUFACTURERS FOR REPACKAGE. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-22F,-30C Decomp Temp:Decomp Text:>1400F Vapor Pres:60648 Vapor Density:4.26 Spec Gravity:1.315 Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUIFIED GAS WITH FAINT ETHEREAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS LIKE POWDERED ALUMINUM, MAGNESIIUM, ZINC, BERILLIUM, ETC. Stability Condition to Avoid:HIGH TEMPERATURES AND OPEN FLAMES Hazardous Decomposition Products:HYDROCHLORIC ACID, HYDROFLUORIC ACID, POSSIBLY CARBONYL CHLORIDE AND CARBONYL FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. RECLAIM BY DISTILLATION OR REMOVE TO A PERMITTED WASTE FACILITY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.