KRYLON DIV SHERWIN-WILLIAMS CO -- S03406 BLUE, QUIK-MARK INVERTED MARKING PAINTS - 1 -- 8010-00N083039
===================== Product Identification ===================== Product ID:S03406 BLUE, QUIK-MARK INVERTED MARKING PAINTS - 1 MSDS Date:09/01/1996 FSC:8010 NIIN:00N083039 === Responsible Party === Company Name:KRYLON DIV SHERWIN-WILLIAMS CO Address:31500 SOLON RD City:SOLON State:OH ZIP:44139 Country:US Info Phone Num:800-247-3266 Emergency Phone Num:216-566-2917 CAGE:JO607 === Contractor Identification === Company Name:KRYLON DIV SHERWIN-WILLIAMS CO Address:31500 SOLON RD Box:City:SOLON State:OH ZIP:44139 Country:US Phone:800-247-3266 CAGE:JO607 Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC. Address:26300 FARGO AVENUE Box:City:BEDFORD HEIGHTS State:OH ZIP:44146 Country:US Phone:216-292-7400 OR 216-595-8634 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE. VP:760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 14% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:HEXANE; (N-HEXANE) (CERCLA). VP:127. CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 8% OSHA PEL:500 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PENTANE, 2-METHYL-; (ISOHEXANE ISOMERS). VP:250. OSHA PEL & ACGIH TLV:500 PPM;1000 PPM STEL (MFR). CAS:107-83-5 RTECS #:SA2985000 Fraction by Wt: 6% OSHA PEL:SEE INGREDIENT ACGIH TLV:SEE INGREDIENT Ingred Name:VM & P NAPHTHA; (V.M. & P. NAPHTHA). VP:12. OSHA PEL:300 PPM;400 PPM STEL (MFR). CAS:64742-89-8 Fraction by Wt: 6% OSHA PEL:SEE INGREDIENT ACGIH TLV:300 PPM (MFR) Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 15% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 2% OSHA PEL:20 MPPCF ACGIH TLV:2 MG/M3 RDUST Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE). OSHA PEL:15 MG/M3 TDUST; 5 MG/M3 RDUST (MFR). CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 3% OSHA PEL:SEE INGREDIENT ACGIH TLV:10 MG/M3 TDUST (MFR) Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 2% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 33.8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS (BAAQMD RULE 49): 49.6% BY WT; 3.43 LBS/GAL. RTECS #:9999999VO Ingred Name:SUPDAT:OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:KETONE. PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CVS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:& REPRO SYS. RATS EXPOS TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. WARNING:THESE PRODS (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:CONTAIN CHEMS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER & BIRTH DEFECTS & OTHER REPRO HARM (CAL (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:PROP 65). NOTE:TOLUENE APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO . RTECS #:9999999ZZ Ingred Name:OTHER PREC:PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMPS >120F. HEAT FROM SUNLIGHT, (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY. USE(ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. THESE COATINGS MAY CNTN MATLS (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 TDUST,(ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:3 MG/M3 (RESPIRABLE FRACTION), OSHA PEL 15 MG/M3 TDUST, 5 MG/M3 (RESPIRABLE FRACTION). ADDN OF REDUCERS/ (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:OTHER ADDITIVES TO THESE PRODUCTS MAY SUBSTANTIALLY ALTER THE COMPOSITION & HAZARDS OF THE PRODUCT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG & RPTD EXPOS TO HEXANE MAY CAUSE DMG TO NERVE TISS OF ARMS & LEGS (PERIPHERAL NEUROPATHY), RSLTG IN MUSCULAR WEAK & LOSS OF SENSATION. THIS EFT MAY BE INCR BY PRESENCE OF METHYL ETHYL (ING 12) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:0.9% Upper Limits:27% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. CLSD CNTNRS MAY EXPLODE (DUE TO BUILD-UP OF PRESS) WHEN EXPOS TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. CONSULT NPFA CODE . USE APPRVD BONDING & GROUNDING(ING 19) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING DRIED FILM, WEAR A NIOSH APPRV D DUST/MIST RESP FOR DUST WHICH (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:PREVENT PRESSURE BUILD-UP & POSSIBLE AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. RESP PROT:MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR ABRASIVE. VENT:1910.94, 1910.107, 1 910.108. EXPLO HAZ:APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. DURING EMERGENCY CONDITIONS (ING 11) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<395F,<202C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.83 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED UNDER THE RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CNTNR. DISP O F I/A/W FED, STATE & LOC REGS REGARDINGPOLLUTION. 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