GLIDDEN COMPANY -- HM 1400 WHITE, AMERICA'S FINEST INT/ACR LATEX SEMI-GLOSS ENA -- 8010-00N091238
===================== Product Identification ===================== Product ID:HM 1400 WHITE, AMERICA'S FINEST INT/ACR LATEX SEMI-GLOSS ENA MSDS Date:12/17/1996 FSC:8010 NIIN:00N091238 === Responsible Party === Company Name:GLIDDEN COMPANY Address:925 EUCLID AVENUE City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:800-221-4100 Emergency Phone Num:800-545-2643 Resp. Party Other MSDS Num.:S3 CAGE:01PD6 === Contractor Identification === Company Name:3E COMPANY Address:4920 CARROLL CANYON ROAD Box:City:SAN DIEGO State:CA ZIP:92121 Country:US Phone:800-451-8346;619-677-0467(FAX) CAGE:EC0MP Company Name:GLIDDEN PAINT, ICI PAINTS NORTH AMERICA Address:925 EUCLID AVE Box:City:CLEVELAND State:OH ZIP:44115 Country:US Phone:800-545-2643/216-344-8207 CAGE:01PD6 ============= Composition/Information on Ingredients ============= Ingred Name:1,2-PROPANEDIOL CAS:57-55-6 RTECS #:TY2000000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:ETHANOL, 2,2'-OXYBIS- CAS:111-46-6 RTECS #:ID5950000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:TITANIUM OXIDE CAS:13463-67-7 RTECS #:XR2275000 Minumum % Wt:10. Maxumum % Wt:20. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:2-PROPENOIC ACID, BUTYL ESTER, POLYMER WITH ETHENYL ACETATE CAS:25067-01-0 Minumum % Wt:10. Maxumum % Wt:20. Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:10. Maxumum % Wt:40. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: IRRIT OF RESP TRACT, LUNGS. PRLNG INHAL MAY LEAD TO MUC MEMB IRRIT, DROW, DIZZ &/LIGHTHEADEDNESS, HDCH, NAUSEA, VOMIT, GI DISTURB, COUGHING, APATHY, CNS DEPRESSION, ANESTHETIC EFFECT/NARCOSIS, BLOOD ABNORMALITIES, KIDNEY DMG, LOSS OF CONSCIOUSNESS. SKIN: IRRIT OF SKIN. PRLNG/RPTD CONTACT CAN CAUSE DERM, DEFATTING. SKIN CONTACT MAY RESULT IN DERMAL ABSORPTION OF COMPONENT(S) OF THIS PROD WHI CH MAY CAUSE APATHY. EYE: IRRIT OF EYES. PRLNG/RPTD CONTACT CAN CAUSE CONJ. INGEST: MAY CAUSE FATIGUE, DROW, DIZZ &/LIGHTHEADEDNESS, HDCH, NAUSEA, VOMIT, DIARR, GI DISTURB, SEVERE ABDOM PAIN, APATHY, CNS DEPRESSION, RESP (EFTS OF OVEREXP) Effects of Overexposure:HLTH HAZ: PROBLEMS, INTOXICATION, CNS DMG, LIVER DMG, KIDNEY DMG, BLADDER DMG, PULM EDEMA, LOSS OF CONSCIOUSNESS, CYANOSIS, ACUTE POISONING, RESP FAILURE, CARDIAC FAILURE, BRAIN DMG, DEATH. SUPPLEMENT AL HEALTH INFO: CNTNS CHEM THAT IS MOD TOX BY INGEST. OTHER EFTS OF OVEREXP MAY INCLUDE TOX TO LIVER, KIDNEY. MAY BE ABSORBED THRU SKIN. SOME LAB TEST RSLTS HAVE SHOWN ETHYLENE GLYCOL TO BE AN ANIMAL TERATOGEN. A STUDY CONDUCTED BY NTP, USING A CONTINUOUS BREEDING PROTOCOL, DEMONSTRATED THAT DIETHYLENE GLYCOL IN DRINKING H*2O AT CONC OF 3.5% (6.1 G/KG/DAY) RSLTD IN DECRD FERTILITY & REPROD PERFORM ANCE IN MICE. (SUPDAT) Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS KIDNEY DISORDERS LIVER DISORDERS NERVOUS SYSTEM DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. REMOVE TO FRESH AIR IF INHALATION CAUSES EYE WATERING, HEADACHES, DIZZINESS/OTHER DISCOMFORT. SKIN: FLUSH FROM SKIN WITH WATER. THEN WASH THOROUGLY WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING. WASH CONTA MINATED CLOTHING BEFORE RE-USE. EYE: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF IRRITATION/OTHER EFFECTS PERSIST, OBTAIN MEDICAL TREATMENT. INGESTION : OBTAIN MEDICAL TREATMENT IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT/FIRE. VAPS ARE HEAVIER THAN AIR & MAY TRAVEL LONG DISTANCES TO SOURCE OF IGNIT & FLASH BACK. VAPS CAN FORM EXPLOS MIXT IN AIR AT ELEVATED TEMP. C LOSED CNTNRS MAY BURST IF EXPOSED TO EXTREME HEAT/FIRE. IN CLOSED TANKS, H*2O/FOAM MAY CAUSE FROTHING/ERUPTION. ================== Accidental Release Measures ================== Spill Release Procedures:COMPLY W/APPLIC HEALTH & ENVIRON REGS. ELIMINATE ALL SOURCES OF IGNIT. VENT AREA. SPILLS MAY BE COLLECTED W/ABSORB MATLS. EVACUATE ALL UNNEC PERS. PLACE COLLECTED MATERIAL IN PROPER CNTNR. LRG SPILLS- SHUT OFF LEAK IF SAFE TO DO SO. DIKE & CNTN SPILL. PUMP TO STORAGE/SALVAGE VESSELS. USE ABSORB TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATL & RINSE H*2O OUT OF SEWERS & H*2O COURSES. (OTHER INFO) ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 100F. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP FROM FREEZING. USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS. Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE. AVOID CONDITIONS WHICH RESULT IN FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING OR ABRADING (SANDING) PAINTED SURFACES. IF SUCH CONDITION S CANNOT BE AVOIDED, USE APPROPRIATE RESPIRATORY PROTECTION AS DIRECTED UNDER SPECIAL PROTECTION INF ORMATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134 Ventilation:PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . IMPERVIOUS CLOTHING AND APRON. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health EFTS OF OVEREXP: THESE EFTS WERE NOT SEEN IN LOWER DOSE LEVELS EVALUATED. SINCE EXPOS RSLTG FROM INCIDENTAL CNTCT IS LIKELY TO BE LOWER BY SEVERAL DEGREES OF MAGNITUDE & ROUTE OF EXPOS USED IN THIS ST UDY DOES NOT REFLECT A LIKELY ROUTE FROM OCCUP/CONSUMER USE. SIGNIFICANCE OF THESE FINDINGS TO HUMANS IS UNCERTAIN. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Spec Gravity:1.19 VOC Pounds/Gallon:229 Appearance and Odor:WHITE. Percent Volatiles by Volume:68.42 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS, REDUCING AGENTS, BASES, ALUMINUM, ZINC, HYDROGEN CHLORIDE, METALS, NITRIC ACID, HYDROFLUORIC ACID, VINYL POLYMERS, METAL COMPOUNDS, HYDROGEN FLUORIDE, MAGNESIUM, SODIUM, POTASSIUM. Stability Condition to Avoid:ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENT, CONTACT WITH ALUMINUM OR ZINC, FREEZING, SPARKS, OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXYGEN, TOXIC GASES. PROPIONALDEHYDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ===================== Ecological Information ===================== Ecological:OTHER INFO: TO PVNT STATIC SPKS, ELEC GROUND & BOND ALL CONTRS & PIPELINES USED IN SHIPPING, TRANSFERRING, REACTING, PRODUCING & SAMPLING OPERATIONS. RESP PROT: TO 40 UG BE/M3. A FULL FACEPIECE, AIR-P URIFYING RESP W/HIGH-EFFICIENCY FILTER IS SUITABLE FOR CONCS UP TO 100 UG BE/M3. A POWERED, AIR-PURIFYING RESP EQUIPPED W/HIGH-EFFICIENCY FILTER, OPERATING IN POS-PRESS MODE, IS SUITABLE FOR CONCS UP TO 1000 UG BE/M3. AN SCBA W/FULL FACEPIECE OPERATED IN PRESS-DEMAND/POS-PRESS MODE IS SUITABLE FOR CONCS >1000 UG BE/M3. FOLLOW OSHA RESP REGS (29 CFR 1910.134). WARNING: AIR-PURIFYING RESPS DO NOT P ROTECT WORKERS IN OXYGEN-DEFICIENT ATMS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. =================== MSDS Transport Information =================== Transport Information:DOT, PROPER SHIPPING NAME: PAINT. ===================== Regulatory Information ===================== State Regulatory Information: ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.