SIRCHIE FINGER PRINT LABORATORIES INC -- SILVER NITRATE CRYSTALS -- 6810-00N092251
===================== Product Identification ===================== Product ID:SILVER NITRATE CRYSTALS MSDS Date:08/18/1998 FSC:6810 NIIN:00N092251 Status Code:A === Responsible Party === Company Name:SIRCHIE FINGER PRINT LABORATORIES INC Address:100 HUNTER PLACE City:YOUNGSVILLE State:NC ZIP:27596 Country:US Info Phone Num:919-554-2244 Emergency Phone Num:919-554-2244 Resp. Party Other MSDS Num.:SN208 CAGE:94514 === Contractor Identification === Company Name:SIRCHIE FINGER PRINT LABORATORIES INC Address:100 HUNTER PLACE Box:City:YOUNGSVILLE State:NC ZIP:27596 Country:US Phone:919-554-2244 CAGE:94514 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER NITRATE CAS:7761-88-8 RTECS #:VW4725000 = Wt:100. OSHA PEL:0.01 MG/M3 ACGIH TLV:0.01 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EDEMA OF THE CONJUNCTIVA AND LIDS, BLOODY PURULENT DISCHARGE FROM THE CONJUNCTIVAL SAC, PERMANENT CORNEAL OPACIFICATION, LOSS OF EPITHELIUM, BLINDNESS, CATARACTOUS LENSES, CORNEAL COLOR CHANGE, KIDNEY AND LIVER DAMAGE, NECROLIZING ULCERATION TO THE GUMS, METHEMOGLOBINEMIA. CHRONIC: ARGYRIA, A BLUE-GREY DISCOLORATION OF THE SKIN, EYES AND MUCOUS MEMBRANES; CONJUNCTIVITIS; EMPHYSEMA; KIDNEY L ESIONS; ARTERIOSCLEROSIS; ANEMIA; NEPHRITIS; RENAL CHANGES; VASCULAR HYPERTENSION. Effects of Overexposure:INHALATION: SORE THROAT, COUGHING, SHORTNESS OF BREATH. INGESTION: PAIN AND BURNING IN THE MOUTH AND THROAT, VIOLENT ABDOMINAL PAIN, VOMITING (POSSIBLE BLACK), NAUSEA, DIARRHEA, DIZZINESS, ANURIA, COL LAPSE, SHOCK, VERTIGO, CONVULSIONS, COMA, DEATH. SKIN: REDNESS, PAIN, ULCERATION, DISCOLORATION. EYES: PAIN, BURNS, DISCOLORATION. Medical Cond Aggravated by Exposure:SKIN, LUNG DISEASES. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED ATTN. INGEST:DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE WATER. (NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS!) GET MED ATTN IMMED. SKIN:FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS. REMOVE CONTAM CLTHG. SEEK MED ATTN. DESTROY CONTAM SHOES. EYES:FLUSH W/PLENTY OF WATER FOR AT LST 1 5 MINS, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLSD. NOTE TO MD'S:ABSORPTION OF SILVER NITRATE INTO BODY LEADS TO FORM OF METHEMOGLOBIN THAT, IN SUFF ICIENT CONCS, CAUSES CYANOSIS. (SUPDAT) ===================== Fire Fighting Measures ===================== Lower Limits:N/E Upper Limits:N/E Extinguishing Media:NONCOMBUSTIBLE. FLOOD WITH WATER ONLY. NO DRY CHEMICAL, CARBON DIOXIDE, OR HALON. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . APPLY FROM AS FAR A DISTANCE AS POSSIBLE. REMOVE CONTAINER FROM FIRE AREA IF WITHOUT RISK. COOL FIRE-EXPOSED CONTAINERS WITH WATER UNTIL W ELL AFTER FIRE IS OUT. Unusual Fire/Explosion Hazard:OXIDIZER. GREATLY INCREASES THE BURNING RATE OF COMBUSTIBLE MATERIALS. NFPA RATING: HEALTH - 3; FIRE - 0; REACTIVITY - 1. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL. WEAR NIOSH APPROVED DUST RESPIRATOR, SAFETY GOGGLES, AND RUBBER GLOVES. STOP LEAK IF WITHOUT RISK. DIKE IF NECESSARY. SWEEP UP AND PLACE IN BAG OR VACUUM UP WITH PROPER FILTER EQUIPPED INSTRUMENT. AVOID CREATING DUST. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. FOR LARGE SPILLS, FLUSH SPILL AREA WITH WATER SPRAY. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER. PROTECT FROM PHYSICAL DAMAGE, AIR, AND LIGHT. AVOID INCOMPATIBLE MATERIALS, ESPECIALLY COMBUSTIBLE MATERIALS. USE ONLY IN WELL-VENTILATED AREAS. AVOID CONTACT WITH SK IN, EYES, AND CLOTHING. AVOID INHALATION. Other Precautions:"EMPTY" CONTAINERS MAY CONTAIN PRODUCT RESIDUE AND MAY BE DANGEROUS. EMPTY CNTNRS SHOULD BE COMPLETELY DRAINED & BUNGED & THEN DISPOSED OF ACCORDING TO LOC, STATE, & FED REGS. MAY CAUSE BURNS OF GI TR ACT. SKIN & EYE IRRITANT. CAUSES SEVERE SKIN & EYE BURNS. EXTREMELY IRRITATING TO RESP TRACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED DUST RESPIRATOR. Ventilation:USE ONLY IN WELL-VENTILATED AREAS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD . Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRST AID PROC: SINCE REVERSION OF METHEMOGLOBIN TO HEMOGLOBIN OCCURS SPONT AFTER TERMINATION OF EXPOS, MOD DEGREES OF CYANOSIS NEED TO BE TREATED ONLY BY SUPPORTIVE MEASURES SUCH AS BED REST & OXYG I NHAL. THORO CLEANING OF ENTIRE CONTAM AREA OF BODY, INCL SCALP & NAILS, IS OF UTMOST IMPORTANCE. IF (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:=443.9C, 831.F Melt/Freeze Pt:=212.2C, 414.F Vapor Pres:NEGLIGIBLE (MM HG) Vapor Density:N/A(AIR=1) Solubility in Water:COMPLETE Appearance and Odor:PURE SOLID, COLORLESS CRYSTALS; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUST MATLS, REDUCING AGENTS, AQ AMMONIA, ACETALDEHYDE, ACETYLENE + AMMONIA, ACETYLIDES (CARBIDES), ACRYLONITRILE, ALCOHOLS, ALKYNES, AMMONIA + ALKALIES, AMMONIUM HYDROXIDE + SODIUM HYDROXIDE, AZIRIDINE, ARSENITES, BROMID Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:NITROGEN OXIDES, SILVER FULMINATE, SILVER ACETYLIDE, EXPLOSIVE COMPOUNDS AND SALTS. Conditions to Avoid Polymerization:DOES NOT OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. =================== Toxicological Information =================== Toxicological Information:POISON. CORROSIVE. MAY BE FATAL IF SWALLOWED. MAY CAUSE SEVERE AND PERMANENT EYE DAMAGE, INCLUDING BLINDNESS. HARMFUL IF INHALED. MAY CAUSE ARGYRIA, A BLUE-GREY DISCOLORATION OF THE SKIN, EYES, AND MU COUS MEMBRANES. CAN PRODUCE METHEMOGLOBIN WHICH, IN SUFFICIENT CONCENTRATION, CAUSES CYANOSIS. MAY CAUSE EMPHYSEMA AND ARTERIOSCLEROSIS. MAY CAUSE KIDNEY AND LIVER DAMAGE. ===================== Ecological Information ===================== Ecological:PREVENT FROM ENTERING SEWERS OR WATERWAYS. HAS A HIGH POTENTIAL TO AFFECT SOME AQUATIC ORGANISMS, SECONDARY WASTE TREATMENT MICROBIAL METABOLISM, AND THE GERMINATION AND/OR EARLY GROWTH OF SOME PLANTS . HAS A LOW POTENTIAL TO PERSIST IN THE ENVIRONMENT AND TO BIOCONCENTRATE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL, STATE & FEDERAL REGULATIONS. DISPOSAL MUST BE I/A/W STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA HAZARDOUS WASTE NO: D001. 100 LB CERCLA SECTION 1 03 REPORTABLE QUANTITY. =================== MSDS Transport Information =================== Transport Information:U.S. DOT: SHIPPING NAME - ID NO., 49-CFR 172.101: SILVER NITRATE - UN 1493. HAZARD CLASS OR DIVISION, 49-CFR 172.101: 5.1 - OXIDIZER. PACKING GROUP, 49-CFR 172.101: PG 11. LABELING REQUIREMENTS 49-CFR 172.101 AND SUBPART E: OXIDIZER. PACKAGING REQUIREMENTS: 49-CFR 173.182. EXCEPTIONS: 49-CFR 173.153. PACKAGING AUTHORIZATIONS: EXCEPTIONS: 49-CFR 173.152. NON-BULK PACKAGING: 49-CFR 173.212. BULK PAC KAGING: 49-CFR 173.240. QUANTITY LIMITATION, 49-CFR 172.101: PASSENGER: AIRCRAFT OR RAILCAR: 5 KG. CARGO AIRCRAFT ONLY: 25 KG. ===================== Regulatory Information ===================== SARA Title III Information:SARA SUB Z 313 HAZARD CATEGORY: ACUTE - YES; CHRONIC - YES; FIRE - NO; PRESSURE - NO; REACTIVIE - NO. THIS MATERIAL IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40 CFR PART 373. Federal Regulatory Information:SILVER-REGULATORY LEVEL: 5.0 MG/L (TCLP-40 CFR 261 APPENDIX II). MATERIALS WHICH CONTAIN THE ABOVE SUBSTANCE AT OR ABOVE THE TCLP REGULATORY LEVEL MEET THE EPA TOXICITY CHARACTERISTICS, AND MUST BE DI SPOSED OF I/A/W 40 CFR PART 262. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.