MALLINCKRODT BAKER INC -- CALCIUM CARBONATE, 4072 -- -
===================== Product Identification ===================== Product ID:CALCIUM CARBONATE, 4072 MSDS Date:05/13/1997 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151 Resp. Party Other MSDS Num.:C0330 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:1-800-582-2537 CAGE:DO803 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CARBONATE CAS:471-34-1 RTECS #:FF9335000 Minumum % Wt:90. Maxumum % Wt:100. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: EXCESSIVE CONCENTRATIONS OF A NUISANCE DUST MAY CAUSE NUISANCE CONDITION SUCH AS COUGHING, SNEEZING, AND NASAL IRRITATION. INGESTION: NON-TOXIC. SKIN: NOT EXPECTED TO BE A HEALTH HA ZARD FROM SKIN EXPOSURE. EYES: NO INFORMATION FOUND, BUT PRESUMED TO CAUSE MECHANICAL IRRITATION. CHRONIC: EXCESSIVE ORAL DOSES OF CALCIUM CARBONATE MAY PRODUCE ALKALOSIS AND HYPERCALCEMIA. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: IF LARGE AMOUNTS WERE SWALLOWED, GIVE WATER TO DRINK AND GET MEDICAL ADVICE. SKIN: WASH EXPOSED AREA WIT H SOAP AND WATER. GET MEDICAL ADVICE IF IRRITATION DEVELOPS. EYES: WASH THOROUGHLY WITH RUNNING WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ADVICE IF IRRITATION DEVELOPS. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN CONTROL MEASURES SECTION. SPILLS: SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WE T SWEEPING MAY BE USED TO AVOID DUST DISPERSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. CONTAINERS OF THIS PRODUCT MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES ( DUST, SOLIDS); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO TEN TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS LOWEST. A NIO SH APPRVD FULL-FACEPIECE DUST/MIST RESP MAY BE WORN UP TO 50 TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (SUP DAT) Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EXPLOYEES EXPOS BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IF GEN PREF BECAUSE IT CAN CTL EMISSIONS OF (OTHER INFO) Protective Gloves:GLOVES. WEAR IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . LAB COAT, APRON OR COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health RESP PROT: WHICHEVER IS LOWEST. FOR EMERS/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMS. PHYSICAL/CHEM PROPERTIES: SOL IN DILUTE ACIDS; DENSITY: 2.7 - 2.95. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=825.C, ######F Solubility in Water:0.001 GM IN 100 ML WATER Appearance and Odor:FINE, WHITE POWDER; ODORLESS. Percent Volatiles by Volume:0 @ 21C/70F ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, FLUORINE, MAGNESIUM WITH HYDROGEN. Stability Condition to Avoid:HEAT, INCOMPATIBLES. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION (825C), EMITS CALCIUM OXIDE FUMES AND LIBERATES CARBON DIOXIDE. =================== Toxicological Information =================== Toxicological Information:NO LD50/LC50 INFORMATION FOUND RELATING TO NORMAL ROUTES OF OCCUPATIONAL EXPOSURE. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROPRIATE & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE/CONTAMINATION OF PRODUCT MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL DISPOSAL REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER & U NUSED PRODUCT I/A/W FEDERAL, STATE & LOCAL REGS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:SARA SECTION 302 RQ/TPQ: NO. SARA SECTION 313 LIST/CHEMICAL CATALOGUE: NO. SARA 311/312: ACUTE: YES; CHRONIC: NO; FIRE: NO; PRESSURE: NO; REACTIVITY: NO (PURE/SOLID). Federal Regulatory Information:CALCIUM CARBONATE, CAS # 471-34-1: LISTED IN TSCA, EC, JAPAN, AUSTRALIA, KOREA, CANADA DSL, PHILIPPINES. NOT LISTED IN CANADA NDSL. RCRA 261.33: NO. TSCA 8 (D): NO. CHEMICAL WEAPONS CONVENTION: NO. TS CA 12 (B): NO. CDTA: NO. AUSTRALIAN HAZCHEM CODE: NO INFORMATION FOUND. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRO DUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.